I think that adding title to the div is the only way for you to do a background image in CSS.
You can cheat a little by then loading a transparent image in the container that the background image is in, make this transparent image have an alt tag and title tag for whatever your background image is about.
If you are doing this for seo purposes this should work, if you are doing it to have the html well formatted, there is only the div tag.
Cheers!
-Erick